Low-density polyethylene (LDPE) is a thermoplastic made from petroleum. It was the first grade of polyethylene, produced in 1933 by Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerisation [1]. Its manufacture employs the same method today. LDPE is commonly recycled[citation needed], and has the number "4" as its recycling symbol.


Properties

LDPE is defined by a density range of 0.910 - 0.940 g/cm³. It is unreactive at room temperatures, except by strong oxidizing agents, and some solvents cause swelling. It can withstand temperatures of 80 °C continuously and 95 °C for a short time. Made in translucent or opaque variations, it is quite flexible, and tough to the degree of being almost unbreakable.[citation needed]

LDPE has more branching (on about 2% of the carbon atoms) than HDPE, so its intermolecular forces (instantaneous-dipole induced-dipole attraction) are weaker, its tensile strength is lower, and its resilience is higher. Also, since its molecules are less tightly packed and less crystalline because of the side branches, its density is lower. LDPE contains the chemical elements carbon and hydrogen.

Chemical resistance
Applications

LDPE is widely used for manufacturing various containers, dispensing bottles, wash bottles, tubing, plastic bags for computer components, and various molded laboratory equipment. Its most common use is in plastic bags. Other products made from it include: